Questions tagged [metallurgy]
Chemical and physical characteristics of metals and alloys.
239
questions
7
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2answers
785 views
How to separate Cu and Ni from alloy containing different metals such as Al, Cu, Ni, (Zn, Pb, Sn < 5%)?
I have an alloy containing different metals such as Al, Cu, Ni, (Zn, Pb, Sn, Ag, Si in small amount < 5%). How can I separate Cu and Ni from this alloy?
I tried to dissolve alloy in sulfuric acid, ...
1
vote
1answer
426 views
Why is the only natural source of radium compounds uranium minerals?
A common mineral of barium is barytes, or barium sulfate ($\ce{BaSO4}$). Because elements in the same periodic group have similar chemical properties, we might expect to and some radium sulfate ($\...
1
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1answer
55 views
What is the alloying composition of the Zinc-Platinum System?
My research team and I are working on a bimetallic alloy consisting of Zinc and Platinum. We have looked for papers regarding the composition of Zinc-Platinum alloy. But there aren't many papers out ...
-1
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1answer
47 views
Why same metal salt is required in electrolytic refining?
Why we use same metal salt in electrolytic refining?
Ex. For $\ce{Cu^2+}$ if we take suppose $\ce{FeSO4}$ so there are 2 ions ready to react on cathode ie $\ce{Fe^2+}$ and $\ce{Cu^2+}$.
But from a ...
1
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1answer
82 views
Why is the formation free energy of carbon dioxide almost constant in Ellingham diagrams?
While reading about Ellingham diagram in my textbook, I noticed that for:
$\ce{C_(_s_) + O2_(_g_) -> CO2_(_g_)}$,
the standard Gibbs free energy ($\ce{\Delta_fG^\circ}$) doesn't seem to vary with ...
1
vote
1answer
66 views
Why are calcination and roasting processes carried out at a temperature just below the ore's fusion temperature?
I had read about the two important methods used for the concentration of an ore - Roasting and Calcination. I have a doubt regarding why both the methods are carried out at temperatures not above the ...
2
votes
1answer
46 views
How thick is the colored oxide layer on heat treated stainless steel? [closed]
When stainless steel is welded, or just heat treated, it will develop a thicker oxide layer, which in some cases is is rainbow colored, but can become so thick as to appear almost black. From the ...
1
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1answer
73 views
Why does Cody use Litharge? [closed]
In many of the precious metal refining videos Cody (Cody's Lab) takes the sample with the precious metal and puts Litharge into it. After heating it in the furnace, while pouring it out the molten ...
8
votes
1answer
213 views
Why are rare earth metals and platinum group metals are often found clustered together in ores
Rare earth and platinum group metals are often found clustered together in the earth's crust. Mining for platinum, for instance, also yields Rhodium and Ruthenium belonging to the same group. Likewise,...
2
votes
1answer
76 views
Roasting of galena
In the metallurgy of $\ce{Pb}$, Galena is first concentrated by froth floatation process. It is then partially roasted to and self reduced to obtain $\ce{Pb}$.
Why is galena only partially roasted(...
0
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0answers
36 views
Calculating change in Gibbs Free Energy for a specific type of problem
Can anyone describe what is going on here?
$$Si(liq.)=Si_{(1 weight percentFe)}$$
I have come across this statement quite a few times in Metallurgical Thermodynamics.All that they ask for is change in ...
1
vote
1answer
47 views
Properties of inconel [closed]
I am doing a project on the physics of the spaceX raptor engine. I believe it is made out of a certain type of inconel alloy. I want to understand why this alloy has the properties that it does, but I ...
7
votes
2answers
348 views
How to refine manganese metal from manganese(IV) oxide found in batteries? [closed]
I opened up some lantern batteries, and inside there's $\ce{MnO2}$ powder, carbon rods, and zinc casings, and other stuff that I don't know what it is exactly. I scraped out $\ce{MnO2}$-containing ...
-1
votes
1answer
85 views
Thinking of reducing aluminum hydroxide with magnesium
Is it possible to reduce aluminum hydroxide to aluminum metal by using a sacrificial magnesium electrode in a single displacement reaction?
I checked my revision of redox charts and it looks like it ...
6
votes
1answer
127 views
Origin of the 15% difference limit between solute and solvent atom radii in the Hume-Rothery rules
According to the Hume-Rothery rules for the substitutional solid solutions the atomic sizes of the the solute and solvent must not differ by more than 15%.
Why should it be so?
1
vote
1answer
71 views
Are there any sulfides, sulfates, carbonates that cannot be dissolved by aqua regia? [closed]
I was looking into these specific minerals: arsenopyrite, pyrite, chalcopyrite, barite, calcite, dolomite. I investigate issues with tellurides not showing expected gold concentrations.
0
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0answers
122 views
Are Alloy Compositions Given in Weight Percent or Atom Percent
Often times I see alloys described like this,
Lockalloy is an alloy that consists of 62% beryllium and 38% aluminum
Are the precentages mentioned here in weight percent or atom percent? Is there a ...
1
vote
2answers
45 views
Thermal properties of aluminium alloy 6063 [closed]
I am looking for the operating temperature range both in a cold and hot environments (minimum and maximum operating temperatures) for aluminium alloy 6063.
I'm new to finding this kind of information ...
-1
votes
1answer
35 views
Can a metal which contains impurity of another metal that is more reactive than itself be electrorefined?
So I know that cathode is made of pure metal and anode of impure. For example take Cu. Cu will be oxidised to Cu+2 at anode and will deposit at cathode.
But now if it contains impurity of , let's say, ...
1
vote
1answer
303 views
What's the difference between Zinc Ascorbate and Zinc Gluconate?
I've been looking at a dental product for pets, called MAXI/GUARD Oral Cleansing Gel and it states it uses zinc ascorbate/taurine, however in the ingredients I found elsewhere it instead lists zinc ...
0
votes
1answer
36 views
Manufacture an artifact with compression
Room-temperature superconductivity has finally been demonstrated, as reported by Quanta (and others), with the caveat that it requires compression of the substrate at nearly 2 Mbar. Obviously, this ...
0
votes
1answer
75 views
Why is there carbon lining on the steel vessel in Hall Heroults process?
I read This answer, and completely understand that why graphite anode is used , but I have read that the vessel acts as the steel cathode but with lining of carbon. What is the need of this carbon ...
0
votes
1answer
167 views
What explains the case hardening color effect?
Year 11 chemistry student here.
I'm curious about how the case hardening effect works on metals.
I know that when the electrons gain an energy 'level' or lose an energy 'level' they emit light at ...
1
vote
2answers
113 views
What lab equipment did Marie Curie use to isolate radium?
My experience in growing crystals for condensed matter physics has been sealing grams of material in ampoules which get heated in laboratory furnaces, so I don't have the experience to understand how ...
3
votes
1answer
618 views
How does liquid gallium interact with a gold leaf
I would like to know what happens when gold leaf comes into contact with liquid gallium. Will the gold dissolve into (alloy with) the gallium, wet the gallium or have no reaction with gallium?
The ...
0
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0answers
91 views
What is the minimum thickness for stainless steel crucible to melt aluminum
I am planning to make a stainless steel crucible (air-tight) to melt aluminum. Aluminum is known to oxidize in presence of air. I therefore want to create a custom crucible made with sheet metal ...
4
votes
1answer
47 views
Home foundry — melting aluminum, mitigating undesirables
I am going to be melting aluminum cylinder head and some soda cans in the home foundry. I am aware the sulphur and the hydrogen present in the melt can make aluminum prone to cracks and brittle.
Are ...
1
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0answers
98 views
Is melting aluminium in the presence of carbon dioxide desirable?
So aluminium cans melting is prone to formation of aluminium oxide due to presence of oxgygen and thin sheet of aluminium (large surface area). To mitigate this I can design a cruicible which is ...
3
votes
2answers
280 views
Why does an mercury ore exist as HgS?
Cinnabar($\ce{HgS}$) is one of the most common ores of mercury.
Why does it not exist at $\ce{HgO}$ or some other such compound?
Is there any reason for why it is so prevalent?
Does it react less ...
3
votes
1answer
43 views
Side product obtained in reduction of cuprous oxide with carbon
So my book sates that in the extraction of cuprous oxide, the following reaction takes place.
$$\ce{Cu2O + C -> 2 Cu + CO}$$
This makes sense to me, if it is seen as the following two reactions ...
0
votes
0answers
23 views
Can metal matrix composites be alloyed after their creation?
I've done a little research on metal matrix composites (MMCs), purely for fun and out of interest. Different types of metal powders are combined with reinforcement materials, to produce a reinforced ...
2
votes
0answers
53 views
Why does 'softening' of lead oxidise only elements other than lead?
In a flowchart describing the steps to refine lead obtained after the reduction step, my book1 gives a short note on the process 'Softening of lead' where the crude lead is melted in the presence of ...
1
vote
1answer
448 views
How many kilograms of graphite are consumed while producing 4 kg of Al through Hall-Heroult process?
How many kilograms of graphite are consumed while producing 4 kg of $\ce{Al}$ through Hall-Heroult process?
This looks like a simple stoichiometry problem:
$$\ce{4Al^3+ + 12e- -> 4Al} \; \; \; \; \...
2
votes
0answers
28 views
How can a minor constituent of an alloy, like carbon in steel have such a profound effect? [closed]
In steel that is 0.65% carbon by weight, barely one in 34 atoms is carbon (assuming no other additives/impurities). How can such an outnumbered constituent make such a big difference? Surely many of ...
6
votes
0answers
70 views
Are platinum metal whiskers very unusual?
Over 20 years ago I pulled my first set of platinum spark plugs out of a car because the engine was missing badly. Two of the six plugs each had one whisker in the gap between electrodes. One crossed ...
5
votes
1answer
803 views
Electrolytic Refining of Silver Nitrate
I read that the electrolytic refining of Silver is done using dilute silver nitrate as an electrolyte and a small percentage of free $\ce{HNO3}$. The following reactions are possible at the anode:
$$\...
5
votes
1answer
80 views
What is the naming convention for Sn and Pb in inter-metallic compounds?
How would one go about naming inter-metallic (specifically, transition post-transition) compounds containing tin and lead?
It is usually easy figuring out the naming of such compounds as they follow ...
4
votes
2answers
605 views
Why is Na+ reduced instead of H+ in the electrolysis of dilute NaCl(aq) with Mercury cathode?
In a class of electrolysis, my instructor told me that Hg forms Na-Hg in the electrolysis of dilute NaCl aqueous solution. For this reason, sodium cations are reduced in the cathode instead of ...
-1
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2answers
2k views
Fumes by Melting Aluminium Soda Cans [closed]
I am planning to melt and cast aluminium from soda cans. I went to quora page that deals with "burning" aluminium can, which can release toxic gases as the cans are coated with plastic inner lining. ...
0
votes
1answer
104 views
What makes metals malleable and ductile? [closed]
Two well-known Physical Properties of metals is that they are malleable and dutile
I was just wondering about what causes metals to be malleable and/or ductile and non-metals to be brittle? What ...
0
votes
1answer
33 views
Reactions of Depressants
In the froth flotation process, the concentration of a sulphide ore takes place using $\ce{NaCN/KCN}$ as a depressant. It forms a soluble complex with the impurity sulphide.
Taking the particular ...
0
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0answers
81 views
Difference between calcination, roasting and pyrolysis
Hie everyone. I have been going through pyrometallurgical processes for recycling lithium-ion batteries and l have been coming across these terms; calcination, pyrolysis and roasting which l need ...
0
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0answers
212 views
Why does copper oxidise if it is considered a “noble metal”?
I'm an electrical engineer and not a chemist, so please excuse me if this is obvious.
When soft-soldering electronic parts, we’re normally taught to clean copper of oxides (like using flux and so on) ...
28
votes
3answers
10k views
Why isn't the American nickel magnetic?
I never thought that modern American nickels actually contained nickel anymore. However, according to this wiki article, the coins actually do contain 25% nickel, the rest being copper. And yet, no US ...
1
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0answers
56 views
Importance of concentration of gold in gold parting
I read following lines about gold parting:
Gold is not attacked by $\ce{H2SO4}$ or $\ce{HNO3}$, but copper and silver dissolve in them, when concentration of gold is less than $30\%$. If however, ...
1
vote
1answer
171 views
Use of Spiegeleisen in manufacture of steel
I recently read the following statements related to Manufacture of steel via Bessemer Process:
When no more $\ce{CO}$ is produced (i.e. blue flame disappears) a calculated amount of Spiegeleisen (...
0
votes
1answer
41 views
Could metal hydride storage tanks for hydrogen store helium as well, given their repective atomic radii? [closed]
With atomic radii very similar, could helium dissolve into metallic foam about as well as hydrogen, thus making metal hydrite hydrogen tanks suitable for helium as well?
0
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2answers
112 views
In pig iron, from where does carbon in it comes from?
I've read that:
"During extraction of iron another impurity appear which is carbon from coke in furnace."
However, I don't understand how there will be enough unreacted carbon that would blend ...
-1
votes
1answer
95 views
Should I be concerned about a galvanic reaction between silver solder and stainless steel?
I would like to solder a drain fitting onto my ultrasonic cleaner's tank. The fitting and the tank are both stainless steel. During its operation, the tank is filled with a cleaning solution and heat ...
4
votes
2answers
775 views
What does it mean to 'fuse' ores and why do we use alkali metals in the process?
For the extraction of chromium, fusion of chromite ore with sodium or potassium carbonate in excess of air is done. What exactly happens in this 'fusion' process?
According to my textbook (class XII ...
